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Polymerization Mechanisms
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What is the primary reason for the variability in lengths of polymer chains formed during free radical polymerization?

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A

The random termination of chain growth due to free radical collisions

B

The uniform addition of monomers without any interruptions

C

The presence of only one type of initiator throughout the process

D

The constant temperature maintained during the reaction

Understanding the Answer

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Free‑radical chains grow until two radicals meet and stop. Other options are incorrect because People think a chain keeps adding monomers one after another without stopping; Having only one kind of initiator does not guarantee equal chain lengths.

Key Concepts

Polymerization mechanisms
Free radical polymerization
Chain termination
Topic

Polymerization Mechanisms

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medium level question

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Definition
Definition

Polymerization mechanisms such as cationic, anionic, and free radical polymerization dictate how polymer chains grow by adding monomers together. These mechanisms involve initiators that induce chain growth through specific chemical reactions, leading to the formation of various types of polymers with distinct properties.

Topic Definition

Polymerization mechanisms such as cationic, anionic, and free radical polymerization dictate how polymer chains grow by adding monomers together. These mechanisms involve initiators that induce chain growth through specific chemical reactions, leading to the formation of various types of polymers with distinct properties.

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