📚 Learning Guide
Phase Diagrams
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In a ternary phase diagram, what occurs at the point where a compound exhibits congruent melting, and how does this relate to the triple point of the same substance?

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Choose the Best Answer

A

The solid phase melts into a liquid of the same composition, which can coexist with both the solid and gas phases.

B

The solid phase decomposes into multiple liquid phases of different compositions.

C

The compound changes from liquid to solid without any change in composition.

D

The gas phase condenses directly into a solid without passing through the liquid phase.

Understanding the Answer

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Answer

In a ternary diagram a congruent melting point is where the liquidus and solidus lines intersect at the same composition, meaning the solid melts directly into a liquid of identical composition without any change in phase proportions. At this point the compound behaves as a pure substance, so the solid, liquid, and any third phase (often another solid or the vapor) can coexist at a single temperature and pressure, forming a triple point. Thus, the congruent melting point is essentially the same as the triple point for that substance because the solid, liquid, and the third phase meet simultaneously. For example, pure NaCl in a NaCl–Na2CO3–NaOH diagram melts congruently at its melting temperature, and the NaCl solid, NaCl liquid, and NaCl vapor all coexist at that same temperature, marking both the congruent melting point and the triple point.

Detailed Explanation

When the solid melts it becomes a liquid of the same composition. Other options are incorrect because This answer says the solid splits into several liquids; This option says the liquid changes composition when it freezes.

Key Concepts

Congruent Melting
Triple Point
Topic

Phase Diagrams

Difficulty

medium level question

Cognitive Level

understand

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