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Polymer Glass Transition Temperature
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Which of the following scenarios best illustrates how variations in molecular weight and chemical composition can affect the glass transition temperature (Tg) and subsequently influence the manufacturing conditions for a polymer used in a medical device?

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A

A polymer with high molecular weight and a high degree of cross-linking, designed for implant applications, requiring higher processing temperatures.

B

A low-density polymer with rapid cooling during processing, resulting in a Tg below room temperature, suitable for packaging.

C

A polymer with low molecular weight and high crystallinity, processed at low temperatures to maintain flexibility for automotive parts.

D

A polymer with a high Tg that is blended with a plasticizer to lower its Tg for easier processing in consumer goods.

Understanding the Answer

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When the polymer chain is long and many chains are linked together, the material behaves more rigidly. Other options are incorrect because Cooling quickly does not change Tg; Tg is set by the polymer’s makeup; A short chain lowers Tg, while crystals make the material more solid and increase Tg.

Key Concepts

Significance of Tg in Polymer Processing
Factors Affecting Tg
Relationship between Tg and Polymer Applications
Topic

Polymer Glass Transition Temperature

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hard level question

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Definition
Definition

Polymer Glass Transition Temperature (Tg) is the temperature at which a polymer transitions from a rigid, glassy state to a flexible, rubbery state. Understanding Tg is crucial as it determines a polymer's properties like flexibility and brittleness, impacting real-world applications such as the Challenger shuttle disaster.

Topic Definition

Polymer Glass Transition Temperature (Tg) is the temperature at which a polymer transitions from a rigid, glassy state to a flexible, rubbery state. Understanding Tg is crucial as it determines a polymer's properties like flexibility and brittleness, impacting real-world applications such as the Challenger shuttle disaster.

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