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Wave-like Behavior of Electrons
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How does the wave-particle duality of electrons relate to the shape and energy levels of atomic orbitals?

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Choose the Best Answer

A

Electrons behave like waves and occupy fixed positions in the orbitals.

B

Electrons exhibit wave-like behavior, which determines the probability distribution within atomic orbitals.

C

Electrons only behave like particles and do not affect the shape of atomic orbitals.

D

Electrons have no relation to atomic orbitals and only exhibit particle behavior.

Understanding the Answer

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Answer

Electrons behave like waves, so when they are confined to an atom they form standing‑wave patterns that satisfy the Schrödinger equation. The allowed standing waves are only those whose wavelengths fit exactly around the nucleus, which gives discrete energy levels and specific shapes for the orbitals. For example, the lowest‑energy “s” orbital is a spherical standing wave with no nodes, while the next “p” orbital has a dumbbell shape with one node, matching the electron’s wave pattern. Because the wave must fit an integer number of half‑wavelengths, only certain energies are possible, explaining why electrons occupy distinct energy shells. Thus, the wave‑particle duality directly determines both the geometry and the quantized energy of atomic orbitals.

Detailed Explanation

Electrons behave like waves. Other options are incorrect because The idea that electrons have fixed positions in orbitals treats them like tiny planets; Thinking that electrons are only particles ignores the wave effect.

Key Concepts

wave-particle duality
atomic orbitals
Topic

Wave-like Behavior of Electrons

Difficulty

medium level question

Cognitive Level

understand

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