📚 Learning Guide
Polymerization Mechanisms
easy

In the context of polymerization mechanisms, the process by which two free radicals collide and form a stable molecule, effectively stopping the growth of the polymer chain, is known as __________.

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Choose the Best Answer

A

Termination

B

Initiation

C

Propagation

D

Chain Transfer

Understanding the Answer

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Answer

The process is called termination by combination. In this step two growing polymer chains, each ending with a free‑radical center, meet and their unpaired electrons pair up, forming a covalent bond that creates a stable, non‑reactive molecule. This reaction removes the radicals from the system, stopping further chain growth. For example, if two radicals R• and R′• combine, they produce a single molecule R–R′, ending both chains. This mechanism is common in radical polymerization of vinyl compounds.

Detailed Explanation

Termination happens when two active ends meet and lock together, forming a stable molecule. Other options are incorrect because Initiation is the first step where radicals are created; Propagation is the step where monomers keep attaching to the growing chain.

Key Concepts

Polymerization mechanisms
Chain growth
Free radical chemistry
Topic

Polymerization Mechanisms

Difficulty

easy level question

Cognitive Level

understand

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