📚 Learning Guide
Polymerization Mechanisms
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Which of the following statements accurately describe the mechanisms of polymerization? Select all that apply.

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Choose the Best Answer

A

Cationic polymerization involves the use of positively charged ions to initiate chain growth.

B

Anionic polymerization can only occur in the presence of strong acids.

C

Free radical polymerization requires an initiator that can generate free radicals.

D

Termination in free radical polymerization can occur when two radicals collide and combine.

E

All types of polymerization result in polymers of the same molecular weight.

Understanding the Answer

Let's break down why this is correct

Answer

Polymerization can happen in two main ways: chain‑growth, where a reactive center keeps adding monomers one after another, and step‑growth, where large molecules link together gradually. In chain‑growth, the reaction starts with an initiator that creates a free radical, cation, or anion; each new monomer attaches to the growing chain, making the chain longer. In step‑growth, every monomer or oligomer can react with any other, so the chain length increases slowly as many small pieces combine. Coordination polymerization uses a metal catalyst to bind monomers and add them one by one, giving precise control over chain length and tacticity. Each mechanism relies on different types of reactive intermediates and dictates the final polymer’s structure and properties.

Detailed Explanation

Option A is true because cationic polymerization starts with a positively charged ion that grabs a monomer. Other options are incorrect because Many people think anionic polymerization requires strong acids, but it actually uses a nucleophile or a base to start the chain; The idea that every polymerization makes the same molecular weight is wrong.

Key Concepts

Polymerization mechanisms
Chain growth
Initiators
Topic

Polymerization Mechanisms

Difficulty

medium level question

Cognitive Level

understand

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