📚 Learning Guide
Polymer Morphology
hard

Why does high-density polyethylene (HDPE) exhibit greater strength compared to low-density polyethylene (LDPE)?

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Choose the Best Answer

A

HDPE has a more linear structure, allowing for closer packing of molecules

B

LDPE has more cross-linking, which weakens the material

C

HDPE is made from different monomers than LDPE

D

LDPE is always produced at higher temperatures than HDPE

Understanding the Answer

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Answer

High‑density polyethylene (HDPE) has straight, tightly packed chains because it has very little branching, so the molecules can line up and crystallize more effectively. This crystallinity creates strong intermolecular forces that resist pulling apart the material. Low‑density polyethylene (LDPE) has many branches that push chains apart, making the material more amorphous and less able to hold forces together. As a result, HDPE can bear heavier loads and is used for pipes, while LDPE, with its flexible, weaker structure, is good for plastic bags. In short, the straight, tightly packed chains of HDPE give it a higher tensile strength than the branched, loosely packed chains of LDPE.

Detailed Explanation

HDPE chains are straight and have very few branches. Other options are incorrect because Cross‑linking is a different process that joins chains together, but LDPE does not have extra cross‑links; it has more branches; Both HDPE and LDPE come from the same monomer, ethylene, so the chemical building blocks are identical.

Key Concepts

Polymer Structure
Material Properties
Polymer Chemistry
Topic

Polymer Morphology

Difficulty

hard level question

Cognitive Level

understand

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