📚 Learning Guide
Polymer Glass Transition Temperature
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Which of the following statements best explains the significance of the glass transition temperature (Tg) in polymers?

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Choose the Best Answer

A

Tg indicates the temperature where a polymer becomes a good electrical conductor.

B

Tg determines the temperature range where a polymer exhibits rubbery behavior, affecting its flexibility and applications.

C

Tg is the temperature at which polymers lose all their molecular weight.

D

Tg signifies the point where polymers become insoluble in solvents.

Understanding the Answer

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Answer

The glass transition temperature tells us when a polymer changes from a hard, glassy state to a softer, rubbery state as it warms. Below Tg the polymer chains are frozen in place and the material behaves like a brittle solid; above Tg the chains can move more freely, making the polymer flexible and tacky. Knowing Tg lets engineers predict how a plastic will perform in different temperatures, such as whether it will crack in cold weather or become sticky in heat. For example, a plastic bottle made from polyethylene terephthalate (PET) has a Tg around 70 °C, so it stays rigid at room temperature but becomes pliable near 80 °C, which is why it can be molded into new shapes when heated. Thus, Tg is a key design parameter that links temperature to mechanical behavior.

Detailed Explanation

Tg is the temperature where a polymer switches from a hard, glassy state to a soft, rubbery state. Other options are incorrect because The idea that Tg means a polymer starts conducting electricity is a misunderstanding; The misconception that polymers lose weight at Tg is incorrect.

Key Concepts

Glass Transition Temperature (Tg)
Polymer Properties
Thermal Behavior of Materials
Topic

Polymer Glass Transition Temperature

Difficulty

medium level question

Cognitive Level

understand

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