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Electronegativity
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How does the Pauling scale of electronegativity influence the prediction of molecular geometry in compounds like water (H2O)?

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Choose the Best Answer

A

It indicates the bond angles in water are 90 degrees

B

It determines the polarity of the H-O bonds, leading to a bent shape

C

It shows that water has a linear molecular geometry

D

It has no effect on molecular geometry

Understanding the Answer

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Answer

The Pauling scale tells us how strongly each atom pulls shared electrons; a larger difference between the electronegativities of two bonded atoms makes the bond more polar, concentrating electron density near the more electronegative atom. In a molecule like H₂O, oxygen’s high electronegativity (3. 44) compared to hydrogen’s (2. 20) creates a strongly polarized O–H bond, leaving the lone pairs on oxygen to repel each other and the bonding pairs. This repulsion between lone pairs and bonding pairs pushes the hydrogen atoms apart, giving the bent (104.

Detailed Explanation

Pauling electronegativity tells how strongly an atom pulls electrons. Other options are incorrect because Some think electronegativity can give exact bond angles like 90°; Some think electronegativity implies a linear shape.

Key Concepts

Pauling scale of electronegativity
applications of electronegativity in predicting molecular geometry
Topic

Electronegativity

Difficulty

medium level question

Cognitive Level

understand

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