📚 Learning Guide
Cycloalkanes Naming
hard

In a bicyclic cycloalkane derivative with two methyl substituents, one on each of the fused rings, determine the correct cis or trans configuration if one methyl is on the equatorial plane of one ring and the other is axial on the adjacent ring. Which configuration is represented?

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Learning Path

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Choose the Best Answer

A

Cis

B

Trans

C

Neither

D

Both

Understanding the Answer

Let's break down why this is correct

Answer

In a fused bicyclic cycloalkane, an equatorial substituent on one ring points roughly outward from that ring, while an axial substituent on the adjacent ring points roughly inward on the opposite face. Because the two rings share a common bond, the outward direction of the equatorial methyl is on the same side of the bicyclic framework as the inward direction of the axial methyl, placing the two groups on opposite sides of the skeleton. This opposite‑face arrangement is defined as the trans configuration. For example, in bicyclo[2. 2.

Detailed Explanation

The methyl on the equatorial plane points downward relative to the ring’s plane. Other options are incorrect because Some might think cis because the rings look similar on the surface; It is a misconception that flipping the rings changes the cis/trans relationship.

Key Concepts

Cycloalkane Derivatives
Cis-Trans Isomerism
Substituent Identification
Topic

Cycloalkanes Naming

Difficulty

hard level question

Cognitive Level

understand

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