📚 Learning Guide
Cycloalkane Conformations
easy

In a cyclobutane molecule, which conformation is expected to exhibit the least torsional strain?

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Learning Path
Learning Path

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Choose the Best Answer

A

The chair conformation

B

The boat conformation

C

The eclipsed conformation

D

The staggered conformation

Understanding the Answer

Let's break down why this is correct

Answer

In cyclobutane the ring is slightly puckered, but the key difference in torsional strain comes from how the hydrogen atoms on adjacent carbons are oriented. A staggered arrangement, where each hydrogen is positioned opposite the hydrogen on the neighboring carbon, avoids the eclipsing interactions that create torsional strain. In contrast, an eclipsed arrangement has the hydrogens directly on top of one another, producing a large amount of torsional strain. Therefore, the staggered conformation is expected to exhibit the least torsional strain. For example, in 1,2-dimethylcyclobutane, the staggered conformation lowers the energy relative to the eclipsed one.

Detailed Explanation

Staggered means each hydrogen points away from its neighbors, so bonds are not twisted together. Other options are incorrect because The chair‑like shape seems to lock the ring but actually puts bonds close together; The boat‑like shape forces the ring to bend upward.

Key Concepts

Torsional Strain
Topic

Cycloalkane Conformations

Difficulty

easy level question

Cognitive Level

understand

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