Learning Path
Question & Answer1
Understand Question2
Review Options3
Learn Explanation4
Explore TopicChoose the Best Answer
A
The chair conformation
B
The boat conformation
C
The eclipsed conformation
D
The staggered conformation
Understanding the Answer
Let's break down why this is correct
Answer
In cyclobutane the ring is slightly puckered, but the key difference in torsional strain comes from how the hydrogen atoms on adjacent carbons are oriented. A staggered arrangement, where each hydrogen is positioned opposite the hydrogen on the neighboring carbon, avoids the eclipsing interactions that create torsional strain. In contrast, an eclipsed arrangement has the hydrogens directly on top of one another, producing a large amount of torsional strain. Therefore, the staggered conformation is expected to exhibit the least torsional strain. For example, in 1,2-dimethylcyclobutane, the staggered conformation lowers the energy relative to the eclipsed one.
Detailed Explanation
Staggered means each hydrogen points away from its neighbors, so bonds are not twisted together. Other options are incorrect because The chair‑like shape seems to lock the ring but actually puts bonds close together; The boat‑like shape forces the ring to bend upward.
Key Concepts
Torsional Strain
Topic
Cycloalkane Conformations
Difficulty
easy level question
Cognitive Level
understand
Practice Similar Questions
Test your understanding with related questions
1
Question 1In a molecule of 1-methylcyclohexane, which conformation minimizes steric hindrance and torsional strain while maximizing stability after a ring flip?
hardChemistry
Practice
2
Question 2Which of the following cycloalkane conformations is characterized by minimal angle strain and torsional strain, making it the most stable form?
easyChemistry
Practice
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