Learning Path
Question & Answer1
Understand Question2
Review Options3
Learn Explanation4
Explore TopicChoose the Best Answer
A
Chair conformation
B
Boat conformation
C
Twist-boat conformation
D
All equatorial conformation
Understanding the Answer
Let's break down why this is correct
Answer
The highest‑energy conformation of cyclohexane is the boat form, because it forces many atoms to be close together, creating severe steric clashes and torsional strain. In the boat shape, several hydrogens on adjacent carbons are forced into gauche positions, causing both eclipsing interactions and 1,3‑dipole repulsions. These repulsions raise the potential energy above that of the chair, which is the most stable conformation. For example, in a boat, two axial hydrogens on the same side of the ring are only about 2. 5 Å apart, far closer than the 3.
Detailed Explanation
The boat shape places many hydrogens close together, causing torsional and steric strain. Other options are incorrect because The chair shape has almost no close hydrogen contacts, so it is the lowest energy conformation, not the highest; The twist-boat shape reduces strain compared to a normal boat by relieving some of the close contacts.
Key Concepts
Conformational Energy Diagrams
Topic
Cycloalkane Conformations
Difficulty
easy level question
Cognitive Level
understand
Practice Similar Questions
Test your understanding with related questions
1
Question 1In a molecule of 1-methylcyclohexane, which conformation minimizes steric hindrance and torsional strain while maximizing stability after a ring flip?
hardChemistry
Practice
2
Question 2When considering chair conformations of cyclohexane, which arrangement of substituents generally leads to the most stable conformation?
hardChemistry
Practice
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