📚 Learning Guide
Cycloalkane Conformations
easy

Which of the following cycloalkane conformations is characterized by minimal angle strain and torsional strain, making it the most stable form?

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Learning Path
Learning Path

Question & Answer
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Choose the Best Answer

A

Chair conformation

B

Boat conformation

C

Twist-Boat conformation

D

Envelope conformation

Understanding the Answer

Let's break down why this is correct

Answer

The most stable cycloalkane conformation is the chair form of cyclohexane, because it keeps each C–C–C angle close to 109. 5° and avoids eclipsing bonds. In the chair, each carbon is sp³ hybridized, so the bond angles match the tetrahedral ideal and no bonds are forced into a higher-energy arrangement. Torsional strain is eliminated because the hydrogens on adjacent carbons are staggered, not eclipsed. For example, in the chair, a hydrogen on one carbon points away from the neighboring carbon’s hydrogen, keeping the molecule relaxed and energetically favorable.

Detailed Explanation

The chair shape keeps bond angles close to the ideal 109.5° and keeps hydrogens out of line with each other, so it has almost no torsional strain. Other options are incorrect because The boat shape forces many hydrogens to be eclipsed, creating torsional strain; The twist‑boat reduces some eclipses compared to the boat, but it still has eclipsing pairs and some angle distortion.

Key Concepts

Cycloalkane Conformations
Stability and Strain in Molecules
Conformational Analysis
Topic

Cycloalkane Conformations

Difficulty

easy level question

Cognitive Level

understand

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