📚 Learning Guide
Cycloalkane Conformations
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Which of the following statements about cycloalkane conformations are true? Select all that apply.

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Choose the Best Answer

A

The chair conformation of cyclohexane is more stable than the boat conformation.

B

Cyclopentane adopts a planar conformation to minimize angle strain.

C

The boat conformation of cyclohexane experiences torsional strain due to eclipsed hydrogens.

D

Puckering in cycloalkanes helps to reduce steric strain.

E

All cycloalkanes have the same level of stability regardless of their conformation.

Understanding the Answer

Let's break down why this is correct

Answer

Cyclohexane’s lowest‑energy form is the chair, which eliminates all eclipsing interactions and places all C–H bonds in staggered positions. The boat form is higher in energy because it contains eclipsing interactions and steric crowding at the “flagpole” hydrogens. A twist‑boat intermediate has less strain than the boat but more than the chair, showing that ring size and torsional strain determine stability. Thus, any statement that identifies the chair as the most stable conformation, notes the boat’s higher energy, or recognizes the twist‑boat as intermediate is correct.

Detailed Explanation

The chair form has no eclipsed bonds, so it has lower torsional strain. Other options are incorrect because Cyclopentane is not flat; a planar ring would force atoms close together and cause angle strain; Not all cycloalkanes are equally stable; the chair is more stable than the boat.

Key Concepts

Cycloalkane Conformations
Stability and Strain in Molecules
Conformational Analysis
Topic

Cycloalkane Conformations

Difficulty

medium level question

Cognitive Level

understand

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