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HomeHomework HelpchemistryPhase Diagrams

Phase Diagrams

Phase diagrams in Chemistry represent the states of matter (solid, liquid, gas) of a substance at different pressures and temperatures. They show how state transitions occur, such as melting, boiling, and sublimation, providing a visual guide to understand the behavior of substances under varying conditions.

intermediate
2 hours
Chemistry
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Overview

Phase diagrams are essential tools in chemistry and material science, providing insights into how substances behave under varying conditions of temperature and pressure. They illustrate the relationships between different phases, such as solid, liquid, and gas, and highlight critical points like the...

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Key Terms

Phase
A distinct state of matter characterized by specific physical properties.

Example: Water exists as solid ice, liquid water, and gas steam.

Triple Point
The unique set of conditions where all three phases of a substance coexist in equilibrium.

Example: The triple point of water occurs at 0.01°C and 611.657 pascals.

Critical Point
The temperature and pressure at which a substance's gas and liquid phases become indistinguishable.

Example: Above the critical point, water cannot exist as a liquid.

Phase Transition
The process of changing from one phase to another.

Example: Melting is a phase transition from solid to liquid.

Gibbs Phase Rule
A formula that relates the number of phases in a system to the number of components and degrees of freedom.

Example: F = C - P + 2, where F is degrees of freedom, C is components, and P is phases.

Equilibrium
A state where the phases of a substance are balanced and stable.

Example: At equilibrium, the rate of evaporation equals the rate of condensation.

Related Topics

Thermodynamics
The study of heat and energy transfer, crucial for understanding phase changes.
intermediate
Material Science
Explores the properties and applications of materials, often using phase diagrams.
advanced
Chemical Equilibrium
Focuses on the balance of chemical reactions, related to phase behavior.
intermediate

Key Concepts

phases of mattertriple pointcritical pointphase transitions