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HomeHomework HelpchemistryIsomerism in Organic Chemistry

Isomerism in Organic Chemistry

Isomerism refers to the phenomenon where compounds with the same molecular formula exhibit different structural arrangements or spatial configurations, leading to distinct chemical and physical properties.

intermediate
3 hours
Chemistry
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Overview

Isomerism is a fundamental concept in organic chemistry that explains how compounds with the same molecular formula can exist in different forms. These forms, known as isomers, can have distinct physical and chemical properties, which is crucial for understanding the behavior of organic compounds. T...

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Key Terms

Isomer
Compounds with the same molecular formula but different structures.

Example: C2H6O can be ethanol or dimethyl ether.

Structural Isomer
Isomers that differ in the connectivity of their atoms.

Example: Butane and isobutane.

Geometric Isomer
Isomers that differ in the spatial arrangement of groups around a double bond.

Example: Cis and trans isomers of 2-butene.

Optical Isomer
Isomers that are non-superimposable mirror images of each other.

Example: Lactic acid has two optical isomers.

Chirality
A property of a molecule that makes it non-superimposable on its mirror image.

Example: A chiral carbon atom has four different substituents.

Conformational Isomer
Isomers that differ by rotation around a single bond.

Example: Staggered and eclipsed forms of ethane.

Related Topics

Stereochemistry
The study of the spatial arrangement of atoms in molecules and its effects on chemical behavior.
intermediate
Functional Groups
Specific groups of atoms that determine the characteristics and reactions of organic compounds.
beginner
Reaction Mechanisms
The step-by-step sequence of events that occur during a chemical reaction.
advanced
Organic Synthesis
The process of constructing organic compounds through chemical reactions.
advanced

Key Concepts

Structural IsomersGeometric IsomersOptical IsomersConformational Isomers