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HomeHomework HelpchemistryChemical Potential and Gibbs Free Energy

Chemical Potential and Gibbs Free Energy

The concept of chemical potential and its relationship with Gibbs free energy, describing how the energy of a system changes with the composition of a mixture, including the Gibbs-Duhem equation and its applications in thermodynamic systems

intermediate
3 hours
Chemistry
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Overview

Chemical potential and Gibbs free energy are fundamental concepts in thermodynamics that help us understand how and why chemical reactions occur. Chemical potential indicates the energy change associated with adding particles to a system, while Gibbs free energy provides insight into the spontaneity...

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Key Terms

Chemical Potential
The change in free energy when an additional particle is added to a system.

Example: In a solution, the chemical potential of a solute affects its concentration.

Gibbs Free Energy
A thermodynamic potential that measures the maximum reversible work at constant temperature and pressure.

Example: The Gibbs free energy change for a reaction can predict if it will occur spontaneously.

Thermodynamic Equilibrium
A state where macroscopic properties do not change over time.

Example: In equilibrium, the rates of forward and reverse reactions are equal.

Phase Transition
The transformation of a substance from one state of matter to another.

Example: Melting is a phase transition from solid to liquid.

Spontaneity
The tendency of a process to occur without external intervention.

Example: Combustion of gasoline is a spontaneous reaction.

Equilibrium Constant
A number that expresses the ratio of products to reactants at equilibrium.

Example: For the reaction A + B ⇌ C, the equilibrium constant K = [C]/([A][B]).

Related Topics

Thermodynamics
The study of energy, heat, and work in chemical systems.
intermediate
Equilibrium Chemistry
The study of chemical reactions at equilibrium and the factors affecting it.
intermediate
Phase Equilibria
The study of the balance between different phases of matter.
advanced

Key Concepts

Chemical PotentialGibbs Free EnergyThermodynamic EquilibriumPhase Transitions